Activated Carbon/ZnFe2O4 Nanocomposite Adsorbent for Efficient Removal of Crystal Violet Cationic Dye from Aqueous Solutions

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Abstract
The aim of this study was to investigate the potential advantage of ZnFe2O4-incorporated activated carbon (ZFAC), fabricated via a simple wet homogenization, on the removal of cationic dye crystal violet (CV) from its aqueous solutions. The as-prepared ZFAC nanocomposite was characterized using Fourier transform infrared (FTIR), X-ray diffraction (XRD), nitrogen adsorption, scanning electron microscope (SEM), thermogravimetric analysis (TGA), and ultraviolet–visible (UV–Vis). Batch adsorption operating conditions such as the pH (3–11), CV concentration (25–200 ppm), ZFAC dose (10–50 mg), temperature (23–45 °C), and contact time were evaluated. The results indicate pH-dependent uptake (optimum at pH 7.2) increased with temperature and CV concentration increase and decreased as adsorbent dose increased. Modeling of experimental data revealed better fit to the Langmuir than Freundlich and Temkin isotherms, with maximum monolayer capacities (Qm) of 208.29, 234.03, and 246.19 mg/g at 23, 35, and 45 °C, respectively. Kinetic studies suggest pseudo-second order; however, the intra-particle diffusion model indicates a rate-limiting step controlled by film diffusion mechanism. Based on the thermodynamic parameters, the sorption is spontaneous (−ΔG°), endothermic (+ΔH°), and random process (+ΔS°), and their values support the physical adsorption mechanism. In addition to the ease of preparation, the results confirm the potential of ZFAC as a purifier for dye removal from polluted water.

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