We have measured the kinetics of low‐pressure chemical vapor deposition of from the decomposition of titanium tetraisopropoxide (TTIP) in the absence of a carrier gas. The deposition rate is second‐order in TTIP at low pressure and high temperature and converts to zero‐order under the reverse conditions. A mechanism is proposed that involves a gas phase bimolecular collision process to produce a reactive intermediate, which subsequently adsorbs and decomposes to produce the product. A rate expression for this mechanism is derived and parameter estimates are obtained by fitting to the kinetic results. The parameter values obtained in this manner for the decomposition of the adsorbed intermediate agree well with the results of temperature‐programmed decomposition of absorbed TTIP on a Cu surface.