Study on Thermal Stability of Gel Foam Co-Stabilized by Hydrophilic Silica Nanoparticles and Surfactants
Open Access
Abstract
The combination of nanoparticles (NP) and surfactant has been intensively studied to improve the thermal stability and optimize the performance of foams. This study focuses on the influence of silica NPs with different concentration on the thermal stability of gel foams based on a mixture of fluorocarbon (FS-50) and hydrocarbon (APG0810) surfactants. The surface activity, conductivity, viscosity, and foaming ability of the APG0810/FS-50/NPs dispersions are characterized. The effects of NP concentration on coarsening, drainage, and decay, as well as of the gel foams under thermal action, are systematically studied. Results show that NP concentration has a significant effect on the molecular interactions of the APG0810/FS-50/NP dispersions. The surface tension and conductivity of the dispersions decrease but the viscosity increases with the increase in NP concentration. The foaming ability of APG0810/FS-50 solution is reduced by the addition of NPs and decreases with the increase in NP concentration. The coarsening, drainage, and decay of the gel foams under thermal action slow down significantly with increasing NP concentration. The thermal stability of the gel foams increases with the addition of NPs and further increases with the increase in NP concentration. This study provides a theoretical guidance for the application for gel foams containing NPs and surfactants in fire-extinguishing agents.Keywords
Funding Information
- National Natural Science Foundation of China (No. 51904230)
- Natural Science Basic Research Program of Shaanxi (No. 2020JQ-755)
- Youth Innovation Team Project of Shaanxi Educational Department (No. 21JP074)
This publication has 57 references indexed in Scilit:
- The search for alternative aqueous film forming foams (AFFF) with a low environmental impact: Physiological and transcriptomic effects of two Forafac® fluorosurfactants in turbotAquatic Toxicology, 2011
- Surface ozonation of polyvinyl chloride for its separation from waste plastic mixture by froth floatationJournal of Material Cycles and Waste Management, 2010
- Foam Drainage in the Presence of Nanoparticle−Surfactant MixturesLangmuir, 2009
- Novel highly fluorinated sulfamates: Synthesis and evaluation of their surfactant propertiesJournal of Colloid and Interface Science, 2008
- Sol–gel synthesis at neutral pH in W/O microemulsion: A method for enzyme nanoencapsulation in silica gel nanoparticlesColloids and Surfaces A: Physicochemical and Engineering Aspects, 2006
- Particles as surfactants—similarities and differencesCurrent Opinion in Colloid & Interface Science, 2002
- Adsorption Mechanism of Conventional and Dimeric Cationic Surfactants on Silica Surface: Effect of the State of the SurfaceJournal of Colloid and Interface Science, 1999
- Kinetics of Adsorption of Cationic Surfactants at Silica-Water InterfaceJournal of Colloid and Interface Science, 1998
- A possible mechanism of stabilization of emulsions by solid particlesJournal of Colloid and Interface Science, 1992
- Surface concentrations and molecular interactions in binary mixtures of surfactantsJournal of Colloid and Interface Science, 1982