Magnetic-Field-Induced Large OER Enhancement in Co-Based Ferrimagnetic Thin Films

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Abstract
Electrochemical water splitting offers a promising route to sustainable hydrogen production, yet the oxygen evolution reaction (OER) remains kinetically sluggish and subject to spin-selection constraints associated with triplet O2. Here, CoTb ferrimagnetic thin films with strong perpendicular magnetic anisotropy (PMA) are used to investigate the relationship between magnetic ordering and OER kinetics. Under a 300 mT magnetic field, the onset potential decreases by ∼96 mV and the Tafel slope by ∼15.1 mV·dec–1, accompanied by reduced charge-transfer resistance. The enhanced OER activity is strongly correlated with magnetic-state regulation and largely retained after field removal. Tb-mediated 3d–4f exchange and strong PMA contribute to regulating and retaining the Co magnetic state, which may influence interactions between Co active sites and oxygen intermediates. This nonvolatile magnetic state may eliminate the need for continuous field application, potentially reducing energy consumption. These findings provide a new perspective for magnetically regulated electrocatalysts.
Funding Information
  • Beihang University
  • Academic Excellence Foundation of BUAA for PHD Students
  • Fundamental Research Funds for the Central Universities
  • Beijing Municipal Natural Science Foundation (JQ23005)
  • National Basic Research Program of China (973 Program) (2022YFA1602700)
  • National Natural Science Foundation of China (NSFC) (52121001)
  • National Natural Science Foundation of China (NSFC) (52271235)
  • National Natural Science Foundation of China (NSFC) (52401300)
  • National Natural Science Foundation of China (NSFC) (52425106)
  • National Natural Science Foundation of China (NSFC) (524B2003)
  • National Natural Science Foundation of China (NSFC) (525B2008)
  • National Natural Science Foundation of China (NSFC) (52601331)
  • National Natural Science Foundation of China (NSFC) (52671300)
  • National Natural Science Foundation of China (NSFC) (U25A20244)

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