Crystal Structures and Raman Spectra of cis‐[SnCl4(H2O)2]·2H2O, cis‐[SnCl4(H2O)2]·3H2O, [Sn2Cl6(OH)2(H2O)2]·4H2O, and [HL][SnCl5(H2O)]·2.5H2O (L=3‐acetyl‐5‐benzyl‐1‐phenyl‐4, 5‐dihydro‐1, 2, 4‐triazine‐6‐one oxime, C18H18N4O2)†
Authors:
- Abdel‐Fattah ShihadaASAbdel‐Fattah Shihada
- Frank WellerFWFrank Weller
- 26 May 2004
- journal article
- research article
- Published by Wiley in Zeitschrift für anorganische und allgemeine Chemie
- Vol. 630 (6) , 841-847
Abstract
The complexes cis‐[SnCl4(H2O)2]·2H2O (1), [Sn2Cl6(OH)2(H2O)2]·4H2O (3), and [HL][SnCl5(H2O)]·2.5H2O (4) were isolated from a CH2Cl2 solution of equimolar amounts of SnCl4 and the ligand L (L=3‐acetyl‐5‐benzyl‐1‐phenyl‐4, 5‐dihydro‐1, 2, 4‐triazine‐6‐one oxime, C18H18N4O2) in the presence of moisture. 1 crystallizes in the monoclinic space group Cc with a = 2402.5(1) pm, b = 672.80(4) pm, c = 1162.93(6) pm, β = 93.787(6)° and Z = 8. 4 was found to crystallize monoclinic in the space group P21, with lattice parameters a = 967.38(5) pm, b = 1101.03(6) pm, c = 1258.11(6) pm, β = 98.826(6)° and Z = 2. The cell data for the reinvestigated structures are: [SnCl4(H2O)2]·3H2O (2): a = 1227.0(2) pm, b = 994.8(1) pm, c = 864.0(1) pm, β = 103.86(1)°, with space group C2/c and Z = 4; 3: a = 961.54(16) pm, b = 646.29(7) pm, c = 1248.25(20) pm, β = 92.75(1)°, space group P21/c and Z = 4.Keywords
This publication has 27 references indexed in Scilit:
- Chiral and Achiral Crystal StructuresHelvetica Chimica Acta, 2003
- Synthesis and x-ray crystal structure of a tin(IV) tetrahalide adduct with a crown etherInorganica Chimica Acta, 1984
- Synthesis and mössbauer studies of some aquo complexes of tin(IV) with crown ethersJournal of Organometallic Chemistry, 1984
- Basicity of transiton metal carbonyl complexes : XIII. Reactions of the π-cyclopentadienyl complexes of molybdenum and tungsten with aprotic acidsJournal of Organometallic Chemistry, 1980
- Role of 1,4-dioxan in solid adducts of hydrated metal halides. Crystal structures of hexa-aquadichloromagnesium-1,4-dioxan(1/1), trans-tetra-aquadibromonickel( II )–1,4-dioxan(1/2), and cis-diaquatetrabromotin( IV )–1,4-dioxan(1/2)J. Chem. Soc., Dalton Trans., 1976
- Stereochemistry of seven-co-ordinate complexes containing a tin–molybdenum bond: crystal structure of [1,2-bis(diphenylphosphino)- ethane]tetracarbonyl(trichlorostannyl)molybdenum(I) aquapentachloro-stannate–benzeneJ. Chem. Soc., Dalton Trans., 1975
- Schwingungsspektren von Dichlorphosphorylmethylamin CH3-NH-P(O)Cl2 und seinen Addukten mit SbCl5 und SnCl4Zeitschrift für anorganische und allgemeine Chemie, 1975
- Addition compound of alkoxy Tin(IV) trichloride with some phosphoryl and amine-oxide ligandsInorganica Chimica Acta, 1972
- Vibrational spectra of concentrated aqueous solutions and solvent extracts of the tin(IV) and antimony(V) chloride systemsJournal of Inorganic and Nuclear Chemistry, 1972
- Addition compounds of aldehydes with tin(IV) halidesJournal of Inorganic and Nuclear Chemistry, 1970