Zero thermal expansion in (1−x)PbTiO3–xBi(Mg,Ti)1/2O3 piezoceramics
- 4 February 2009
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 19 (11) , 1648-1652
Abstract
The compounds (1−x)PbTiO3–xBi(Mg,Ti)1 /2O3 (x = 0–0.7) were prepared in order to hunt for low thermal expansion piezoceramics, in particular for zero thermal expansion over a wide temperature range. The negative thermal expansion of PbTiO3 was much weakened by forming a solid solution with Bi(Mg,Ti)1 /2O3. Solutions of (1−x)PbTiO3–xBi(Mg,Ti)1 /2O3 with x = 0.2 and x = 0.4 exhibited zero thermal expansion covering a wide temperature range (from RT to about 500 °C). The (1−x)PbTiO3–xBi(Mg,Ti)1 /2O3 ceramics had high density and their mechanical performances were satisfactory with high fracture toughness. The promising applications of the zero thermal expansion materials (1−x)PbTiO3–xBi(Mg,Ti)1 /2O3 are due to its high piezoelectric d33, controllable thermal expansion, and high thermal stability.Keywords
This publication has 34 references indexed in Scilit:
- Structure and enhancement of negative thermal expansion in the PbTiO3–CdTiO3 systemApplied Physics Letters, 2005
- Synthesis and thermal expansion of ZrO2/ZrW2O8 compositesJournal of the European Ceramic Society, 2005
- Zero-expansion planNature, 2003
- Phase transition and negative thermal expansion in A2(MoO4)3 system (A=Fe3+, Cr3+ and Al3+)Journal of Alloys and Compounds, 2002
- Fabrication of near-zero thermal expansion (FexSc1−x)2Mo3O12–MoO3 ceramic composite using the reaction sintering processMaterials Science and Engineering: A, 2001
- Phase transition energetics and thermodynamic properties of ferroelectric PbTiO3Journal of Materials Research, 1998
- A new look at grain size and load effects in the hardness of ceramicsMaterials Science and Engineering: A, 1998
- Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW 2 O 8Science, 1996
- Negative thermal expansion ceramics: A reviewMaterials Science and Engineering, 1987
- X-Ray Study of the Phase Transition in Lead TitanatePhysical Review B, 1950