Synthesis and crystal and molecular structure of (Et 4 N) 2 [Mn 10 O 2 Cl 8 {(OCH 2 ) 3 CMe} 6 ]·4MeOH·2H 2 O, a Mn II,III mixed-valence cluster with the decametallate core geometry
Authors:
- Michael CavaluzzoMCMichael Cavaluzzo
- Qin ChenQCQin Chen
- Jon ZubietaJZJon Zubieta
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 131-133
Abstract
The reaction of (Et4N)2MnCl4 with MeC(CH2OH)3 in acetonitrile in the presence of atmospheric oxygen yields the oxoalkoxomanganese cluster (Et4N)2[Mn10O2Cl8{(OCH2)3CMe}6]·4MeOH·2H2O, a MnII,III mixed valence species exhibiting the decametallate core geometry, {M10O2L26}.Keywords
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