Fourier-transform infrared photoacoustic studies of hydrogenated diamond surfaces

Authors:
  • TAToshihiro Ando
    Toshihiro Ando
  • SISatoru Inoue
    Satoru Inoue
  • MIMotohiko Ishii
    Motohiko Ishii
  • MKMutsukazu Kamo
    Mutsukazu Kamo
  • YSYoichiro Sato
    Yoichiro Sato
  • OYOsamu Yamada
    Osamu Yamada
  • TNTatsuhiko Nakano
    Tatsuhiko Nakano

Abstract
Fourier-transform infrared photoacoustic spectroscopy (FTIR-PAS) is shown to be a useful tool for structural studies of hydrogen and/or oxygen chemisorption on the surface of diamond powders. As compared with the diffuse reflectance method or the KBr pellet method, it has become clear that PAS has an advantage in terms of surface sensitivity. The possibility of quantitative analysis of chemisorbed hydrogen has also been demonstrated.