One teflon ® -like channelled nanoporous polymer with a chiral and new uninodal 4-connected net: sorption and catalytic properties
- 25 January 2005
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1291-1293
Abstract
Zn(C17H8F6O4) is the first example of a fluoro-lined nanotube organo-inorganic 3D polymeric chiral structure, which possesses two different types of isolated channels, one of them being laid out with a double spiral of CF3-groups from the ligand molecule; the structure is a new uninodal 4-connected net that only exists when bent ligands connect the centres, and the compound exhibits selective sorption and catalytic chiral recognition properties.Keywords
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