Aroylchlorination of 1,6-Dienes via a Photoredox Catalytic Atom-Transfer Radical Cyclization Process
Authors:
- 15 October 2019
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 21 (21) , 8615-8619
Abstract
A method using aroyl chlorides as atom-transfer radical cyclization agents in a novel visible-light photocatalytic aroylchlorination reaction is developed. The overall transformation involves the formation of two new C–C bonds and one new C–Cl bond in a one-pot process. The advantages of this reaction include high atom/step/redox economy, mild conditions, operational simplicity, and broad substrate scopes.Keywords
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