Design, Synthesis, and X‐Ray Crystal Structure of a Fullerene‐Linked Metal–Organic Framework
Authors:
- 13 November 2013
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 126 (1) , 164-167
Abstract
Given the unique structural and electronic properties of C60, metal–organic frameworks (MOFs) containing C60 linkers are expected to exhibit interesting characteristics. A new hexakisfullerene derivative possessing two pairs of phenyl pyridine groups attached to two methano‐carbon atoms located at the trans‐1 positions was designed and synthesized. The four pyridyl nitrogen atoms define a perfectly planar rectangle. This new C60 derivative was used to assemble the first fullerene‐linked two‐dimensional MOF by coordination with Cd2+.Keywords
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