A facile approach for fabricating fluorescent cellulose
Authors:
- 12 May 2010
- journal article
- research article
- Published by Wiley in Journal of Applied Polymer Science
- Vol. 117 (6) , 3639-3644
Abstract
Fluorescent cellulose nanocrystals (CNCs) were prepared through a two‐step approach. Reactive amino groups were first introduced onto the CNCs through a silanization reaction with 3‐aminopropyltrimethoxysilane. The fluorescent moieties were then attached onto the cellulose by covalent grafting between the amino groups and 1‐pyrenebutyric acid N‐hydroxy succinimide ester or fluorescein isothiocyanate. The synthesized fluorescent CNCs were investigated and characterized with attenuated total reflectance Fourier transform infrared spectroscopy, ultraviolet–visible absorbance and fluorescence spectroscopy, confocal microscopy, and dynamic light scattering. The same fluorescent functionalization strategy could also be applied to other cellulose materials, such as microcrystalline cellulose and bulky paper sheets. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010Keywords
This publication has 24 references indexed in Scilit:
- Polymer Nanocomposites with Nanowhiskers Isolated from Microcrystalline CelluloseBiomacromolecules, 2009
- Fluorescent Labeling of Biomolecules with Organic ProbesChemical Reviews, 2008
- Highly Filled Bionanocomposites from Functionalized Polysaccharide NanocrystalsBiomacromolecules, 2008
- Fluorescently Labeled Cellulose Nanocrystals for Bioimaging ApplicationsJournal of the American Chemical Society, 2007
- Morphology and Structure of Crystalline Polysaccharides: Some Recent StudiesMacromolecular Symposia, 2005
- Comparison of the oxygen sensor performance of some pyrene derivatives in silicone polymer matrixSensors and Actuators B: Chemical, 2004
- Rodlike Cellulose Microcrystals: Structure, Properties, and ApplicationsMacromolecular Rapid Communications, 2004
- Monomolecular Layers of Pyrene as a Sensor to Dicarboxylic AcidsThe Journal of Physical Chemistry B, 2004
- Mortalin imaging in normal and cancer cells with quantum dot immuno-conjugatesCell Research, 2003
- Cellulose Crystallites: A New and Robust Liquid Crystalline Medium for the Measurement of Residual Dipolar CouplingsJournal of the American Chemical Society, 2000