Total Synthesis of Herboxidiene/GEX 1A
Authors:
- 13 July 2007
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 9 (16) , 3141-3143
Abstract
A convergent enantioselective synthesis of herboxidiene/GEX 1A (1) is described that features a double stereodifferentiating crotylation, [4 + 2] annulation, and a silicon-based sp2−sp2 cross-coupling to assemble the conjugated diene.Keywords
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