Synthesis of polyvinyl acetate‐graft‐poly‐2‐oxazolines

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Abstract
Poly(vinyl acetate‐co‐vinyl chloroformate) (1) was synthesized via phosgenation of poly(vinyl acetate‐co‐vinyl alcohol). It was shown that (1) is capable of initiating the polymerization of 2‐phenyl‐2‐oxazoline and 2‐methyl‐2‐oxazoline, when the counter ion is exchanged using potassium iodide. Polyvinyl acetate‐graft‐poly‐2‐phenyl‐2‐oxazoline and polyvinyl acetate‐graft‐poly‐2‐methyl‐2‐oxazoline are obtained in the grafting reaction.

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