On the appearance of resonances in reactive scattering: An experimental study of the H+D2→HD+D reaction at collision energies near 1.29 eV

The hydrogen exchange reaction ${\mathrm{H+D}}_{\mathrm{2}}\text{(v=0,j=0)→}\mathrm{HD}{\mathrm{(v}}^{\prime }{\mathrm{,j}}^{\prime }\mathrm{)+}$ D was investigated at collision energies between 1.27 and 1.30 eV in a high resolution crossed beam experiment. The angle-velocity distribution of nascent D-atoms was measured using the technique of Rydberg atom time-of-flight spectroscopy. The resolution of this technique allows the identification of individual ro-vibrational states of the associated HD product molecule. Calculations done on the Liu–Siegbahn–Truhlar–Horowitz (LSTH) potential energy surface (PES) explicitly including the Geometric Phase effect predict a resonance in reactive scattering for collision energies close to 1.29 eV. The experimental data do not show signatures of this resonance in the energy range investigated. Instead of this a general good agreement between experiment and theory even on the basis of state-to-state differential cross sections is already found for calculations on the LSTH PES at a collision energy of 1.30 eV not including the Geometric Phase indicating that this effect does not play an important role at these collision energies.