The Reaction of Carbon Monoxide with Organometallic Compounds.
Authors:
- 1 March 1964
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 37 (3) , 341-343
Abstract
The reaction of iron pentacarbonyl with aryllithiums at −50∼60°C has yielded the corresponding aromatic aldehydes in good yields. 2,6-Dimethylbenzaldehyde (36.4%), 2,4-dimethylbenzaldehyde (65.4%), p-t-butylbenzaldehyde (47.0%), o-t-butylbenzaldehyde (54.3%), p-methoxybenzaldehyde (24.2%) and 2,4,6-trimethylbenzaldehyde (60.5%) have been prepared by this method.Keywords
This publication has 2 references indexed in Scilit:
- The Reaction of Carbon Monoxide with Organometallic Compounds. VI. Synthesis of Symmetrical Ketones by the Reaction of Carbon Monoxide with Organolithium CompoundsBulletin of the Chemical Society of Japan, 1962
- On the Formation of Benzoin by the Reaction of Carbon Monoxide with Organometallic CompoundsBulletin of the Chemical Society of Japan, 1961