Reactive Processing of Thermoplastic Polymers: A Review of the Fundamental Aspects
Authors:
- 1 July 2007
- journal article
- review article
- Published by Walter de Gruyter GmbH in International Polymer Processing
- Vol. 22 (3) , 218-258
Abstract
The review is devoted to the fundamental aspects of the reactive processing of thermoplastic polymers. First of all, some reactive processing examples, including polymer grafting (vinyl silane, maleic anhydride) and/or functionalization, bulk polymerization (urethane, lactams, acrylate, ∊-capolactone), polyester modification and new copolymers synthesis, are presented. From a fundamental point of view, the review covers the state of the art in the domains of rheology (specifically modelling of rheo-kinetics), diffusion and mixing in highly viscous reactive or non reactive media. Finally, 1, 2 and 3-D simulation of the reactive extrusion process in twin-screw extruder is reported at the end of the review.Keywords
This publication has 323 references indexed in Scilit:
- Reactive copolymerization of various monomers based on lactams and lactones in a twin‐screw extruderJournal of Applied Polymer Science, 2005
- UV fluorescence monitoring of the mixing of molten polymers in a batch mixerPolymer Engineering & Science, 2003
- Reactive modification of polyethylene terephthalate with polyepoxidesPolymer Engineering & Science, 2001
- Rheokinetics and the influence of shear rate on the Trommsdorff (gel) effect during free radical polymerizationPolymer Engineering & Science, 2001
- Reactive compatibilization and in‐line morphological analysis of blends of PET and a thermotropic liquid crystalline polymerPolymer Engineering & Science, 2001
- Viscoelastic characteristics of chain extended/branched and linear polyethylene terephthalate resinsJournal of Applied Polymer Science, 2000
- Correlation of linear viscoelastic behavior and molecular weight evolution in the bulk urethane polymerizationJournal of Applied Polymer Science, 1997
- Development and control of a blend morphology by In situ cross‐linking of the dispersed phaseJournal of Applied Polymer Science, 1994
- Solid‐state polycondensation of poly(ethylene terephthalate) recycled from postconsumer soft‐drink bottles. I.Journal of Applied Polymer Science, 1993
- Chain extenders for polyesters. III. Addition-type nitrogen-containing chain extenders reactive with hydroxyl end groups of polyestersJournal of Applied Polymer Science, 1986