Design and synthesis of phosphole-based π systems for novel organic materials
- 27 January 2009
- journal article
- perspective
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 7 (7) , 1258-1271
Abstract
Phospholes are known to exhibit characteristic optical and electrochemical properties derived from the phosphorus-bridged 1,3-dienic π system. Particular interest has recently been paid to their π-conjugated derivatives, such as non-fused phospholes, dibenzo[b,d]phospholes, benzo[b]phospholes, benzo[c]phospholes and related compounds. This perspective focuses on recent advances in the synthesis of these phosphole-based π systems with representative examples that would give valuable guidelines for designing phosphole-containing opto-electrochemical materials.Keywords
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