Microstructural Evolution and Electrochemical Behavior of Solution Treated, Hot Rolled and Aged MgDyZnZr Alloy
Authors:
- Bruno Xavier de FreitasBFBruno Xavier de Freitas
- Leonardo A. AntoniniLALeonardo A. Antonini
- Paula L. C. T. CuryPCPaula L. C. T. Cury
- Viviane L. F. da SilvaVSViviane L. F. da Silva
- Nabil ChaiaNCNabil Chaia
- Célia R. TomachukCTCélia R. Tomachuk
- Stéphane MathieuSMStéphane Mathieu
- Gilberto C. CoelhoGCGilberto C. Coelho
- Claudinei dos SantosClaudinei dos Santos
- Carlos A. NunesCNCarlos A. Nunes
Open Access
Abstract
In order to develop a potential route to fabricate plates and clips for orthopedic applications, a Mg–3.4Dy–0.2Zn–0.4Zr (wt.%) alloy was produced and analyzed in different conditions: solution treated at 525 °C for 3 h, hot rolled and hot rolled and aged at 250 °C. The aging behavior of the rolled alloy was investigated during isothermal aging at 250 °C, and a significant peak was observed at 10 h. The electrochemical behavior was evaluated in 0.9 wt.% NaCl solution at 37 ± 0.5 °C by potentiodynamic polarization and electrochemical impedance spectroscopy. The 525 °C-3 h and hot rolled specimens exhibited corrosion rates of 2.0 and 1.7 mm/year, respectively. The hot rolled and aged at 250 °C for 10 h specimen presented a grain size of 11.8 ± 1.7 μm with an intense macrotexture of the basal {0002} plane, hardness of 73 ± 3 HV and higher impedance modulus and obtained the highest corrosion resistance with a corrosion rate of 0.9 mm/year.Keywords
Funding Information
- Fundação de Amparo à Pesquisa do Estado de São Paulo (2017/17257-5, 2018/20375-2)
- Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (Finance Code 001)
- Conselho Nacional de Desenvolvimento Científico e Tecnológico (142337/2019-6)
This publication has 43 references indexed in Scilit:
- Chemical Elements of Human Bone Tissue Investigated by Nuclear Analytical and Related MethodsBiological Trace Element Research, 2013
- Structural Changes of Precipitates by Aging of an Mg-4 at%Dy Solid Solution Studied by Atomic-Scaled Transmission Electron MicroscopyMATERIALS TRANSACTIONS, 2011
- Accumulation of rare earth elements in human bone within the lifespanMetallomics, 2011
- The history of biodegradable magnesium implants: A review☆Acta Biomaterialia, 2010
- Evaluation of short-term effects of rare earth and other elements used in magnesium alloys on primary cells and cell lines☆Acta Biomaterialia, 2010
- In vitro corrosion and biocompatibility of binary magnesium alloysBiomaterials, 2009
- Progress and Challenge for Magnesium Alloys as BiomaterialsAdvanced Engineering Materials, 2008
- Chemistry of nanoscale precipitates in Mg–2.1Gd–0.6Y–0.2Zr (at.%) alloy investigated by the atom probe techniqueMaterials Science and Engineering: A, 2005
- Characterisation of strengthening precipitate phases in a Mg–Y–Nd alloyActa Materialia, 2000
- Pharmacology and toxicology of dysprosium, holmium, and erbium chlorides*1Toxicology and Applied Pharmacology, 1966