The Transition Metal‐Nitrogen Multiple Bond
Authors:
- Kurt DehnickeKDKurt Dehnicke
- 1 May 1981
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 20 (5) , 413-426
Abstract
Numerous nitrido complexes of transition metals show very short metal‐nitrogen bond lengths, suggesting MN‐triple bonds. At present, compounds of this type are being intensively investigated. In particular the molybdenum complexes are considered as model substances for the study of at least an intermediate step of N2‐assimilation. This article contains a review of the structure and bonding, as well as syntheses and reactions of these complexes.Keywords
This publication has 87 references indexed in Scilit:
- N‐Halogen‐Vanadiumnitridchloride, Cl3VN - X, mit X = Br, IZeitschrift für anorganische und allgemeine Chemie, 1979
- The reactions of transition metal nitrides of groups IVA, VA and VIA with chlorine, bromine and hydrogen chlorideJournal of Inorganic and Nuclear Chemistry, 1977
- Metal-metal interactions involving metalloporphyrins. III. Conversion of tetraphenylporphinatoiron(III) azide to an N-bridged hemin dimerJournal of the American Chemical Society, 1976
- The crystal structure of tetraphenylarsonium nitridotetraiodo-osmate(VI): A high-oxidation-state lodo complex of square-pyramidal osmiumTransition Metal Chemistry, 1975
- Coordination chemistry of nitric oxideAccounts of Chemical Research, 1975
- Synthesis, structure and bonding of a sulphur-bridged alkyl imido dimerlc complex of molybdenum(V)Journal of the Less Common Metals, 1974
- Über die Darstellung der Tetrachloridazide von Niob und Tantal. Die Kristallstruktur von Tantaltetrachloridazid TaCl4N3Zeitschrift für anorganische und allgemeine Chemie, 1974
- Infra-red spectrum and force constants of the nitridorhenate(VII) ionJournal of Inorganic and Nuclear Chemistry, 1968
- Normalkoordinatenanalyse von ReO3N2−, ReO3S−, ReO3,Cl und ReO3BrSpectrochimica Acta Part A: Molecular Spectroscopy, 1967
- An electronic interpretation of the trans effect in platinous complexesJournal of Inorganic and Nuclear Chemistry, 1956