Complexes with Dative Bonds between d‐ and s‐Block Metals: Synthesis and Structure of [(Cy3P)2Pt-Be(Cl)X] (X=Cl, Me)
- 19 May 2009
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 48 (23) , 4239-4241
Abstract
A platinum–beryllium adduct (see structure) was prepared by the reaction of [Pt(PCy3)2] and BeCl2. Treatment with methyllithium resulted in ligand substitution at the beryllium center. Both complexes were structurally characterized and display unprecedented two‐center two‐electron bonds between a transition metal and beryllium. magnified imageKeywords
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