Solid state synthesis under supramolecular control of a 2D heterotetratopic self-complementary tecton tailored to halogen bonding
- 31 July 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry
- Vol. 30 (10) , 1397-1402
Abstract
We describe the synthesis and characterization, by single crystal X-ray analysis, of a 1D heteroditopic self-complementary tecton for halogen bonding. It was designed to also incorporate double bonds and to possess heteropolar π–π stacking groups in order to carefully control its supramolecular organization in the solid state. As a result of this supramolecular control, by UV irradiation in the solid state the compound dimerizes forming a 2D heterotetratopic self-complementary tecton tailored to halogen bonding based self-assembly. This 2D tecton crystallizes clathrating chloroform molecules.Keywords
This publication has 44 references indexed in Scilit:
- Pentaerythritol tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl) ether: a tecton for the self-assembly of double strand 1D infinite chainsJournal of Fluorine Chemistry, 2004
- A convenient preparation of 2,3,5,6-tetrafluoro-4-iodo-benzaldehyde and its application in porphyrin synthesisJournal of Fluorine Chemistry, 2004
- Halogen Bonding and π···π Stacking Control Reactivity in the Solid StateJournal of the American Chemical Society, 2004
- Synergistic effects in controlling excited-state photodimerisation using multiple supramolecular interactionsDedicated to Professor J.-M. Lehn on the occasion of his 65th birthday.Chemical Communications, 2004
- A green chemistry approach to the synthesis of a crystalline organic inclusion compoundGreen Chemistry, 2003
- Supramolecular control of [2 + 2] photodimerization via hydrogen bondingPhotochemical & Photobiological Sciences, 2003
- Diastereospecific Photochemical Dimerization of a Stilbene‐Containing Daisy Chain Monomer in Solution as well as in the Solid StateAngewandte Chemie International Edition, 2003
- 4,15-Diamino[2.2]paracyclophane, a Reusable Template for Topochemical Reaction Control in SolutionEuropean Journal of Organic Chemistry, 2002
- Host-Guest Chemistry Aids and Abets a Stereospecific Photodimerization in the Solid StateAngewandte Chemie International Edition, 2001
- Studies in crystal engineering: crystal packing, topological photodimerization and structure–reactivity correlations in fluoro-substituted styrylcoumarinsJournal of the Chemical Society, Perkin Transactions 2, 1997