Design and initial characterization of an inlet for gas‐phase NOy measurements from aircraft

Authors:
  • TRT. B. Ryerson
    T. B. Ryerson
  • LHL. G. Huey
    L. G. Huey
  • KKK. Knapp
    K. Knapp
  • JNJ. A. Neuman
    J. A. Neuman
  • DPD. D. Parrish
    D. D. Parrish
  • DSD. T. Sueper
    D. T. Sueper
  • FFF. C. Fehsenfeld
    F. C. Fehsenfeld
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Abstract
An understanding of gas‐phase HNO3 transmission through an inlet is necessary to evaluate the quality of NOy measurements from an aircraft platform. A simple, inexpensive, low‐volume Teflon inlet is described and its suitability as an aircraft inlet for gas‐phase NOy is assessed. Aerosol transmission is not characterized, but inlet design and orientation probably discriminates against the majority of aerosol by mass. Laboratory data, in‐flight HNO3 standard addition calibrations, and ambient NOy measurements from the 1997 North Atlantic Regional Experiment aircraft mission are used to characterize inlet transmission efficiencies and time constants. Laboratory tests show high transmission efficiencies for HNO3 which are relatively independent of ambient temperature and humidity. In‐flight standard addition calibrations were carried out at ambient temperatures ranging from −20° to +8°C and relative humidities from 3% to 71%. These data suggest that nearly all the sampled air contacts an inlet surface, with 90% of added HNO3 being transmitted in ∼1.5 s. Ambient data are presented to demonstrate negligible hysteresis in 1‐Hz NOy measurements, relative to variability observed in ozone data, from an air mass where HNO3 is expected to be a large fraction of the total NOy. Power spectra of ambient NOy (at temperatures from −35° to +35°C and relative humidities from 3% to 100%) and ozone measurements suggest an effective NOy instrument time constant of ∼2 s.

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