Synthesis of Boron-Iodinated o-Carborane Derivatives. Water Stability of the Periodinated Monoprotic Salt
- 28 March 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 45 (9) , 3496-3498
Abstract
Boron periodination of o-carborane has been achieved by taking account of the fact that B atoms in the cluster are of two types, i.e., those adjacent to both C atoms and the remainder. The high number of nonequivalent leaving groups opens the possibility through B−C coupling to materials with novel possibilities and to self-assembling due to the enhanced polarizability of the C−H bond. Periodination has accentuated the acidity of the carborane, and monoprotic salts are stable in water.Keywords
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