Chiral 1, 4‐Benzodiazepin‐2‐one, template for enantioselective synthesis of α‐amino acids and their α‐deuterio congeners. Preliminary communication
Authors:
- 10 June 1981
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 64 (4) , 1145-1149
Abstract
Absolute conformation of 7‐chloro‐5‐phenyl‐1‐[(S)‐α‐phenylethyl]‐1, 3‐dihydro‐2H‐1, 4‐benzodiazepin‐2‐one (1c) in crystal, and its inversion rate in solution were determined, enabling prognosis of direction of asymmetric induction during C(3)‐alkylation.Keywords
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