Sunlight-Driven Forging of Amide/Ester Bonds from Three Independent Components: An Approach to Carbamates
Authors:
- 18 October 2016
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 18 (21) , 5572-5575
Abstract
A photoredox catalytic route to carbamates enabled by visible irradiation (or simply sunlight) has been developed. This process leads to a novel approach to the construction of heterocyclic rings wherein the amide or ester motifs of carbamates were assembled from three isolated components. Large-scale experiments were realized by employing continuous flow techniques, and reuse of photocatalyst demonstrated the green and sustainable aspects of this method.Keywords
Funding Information
- Ministry of Education of the People's Republic of China (HIT.BRETIV.201310)
- National Natural Science Foundation of China (21372055, 21472030, 21672047)
- State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology (2015DX01)
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