Ammonia volatilization, nitrous oxide emissions, and corn yields as influenced by nitrogen placement and enhanced efficiency fertilizers

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Abstract
Ensuring sufficient fertilizer nitrogen (N) for crops while minimizing N losses requires best management practices optimized for climate, crop, soil, and root zone hydrology. In Ontario, pre‐plant N fertilization of corn ( Zea mays L.) is common; however, this practice extends the time between application and significant root interception of N by the plant, potentially increasing the risk of N loss through soil nitrous oxide emissions, ammonia (NH 3 ) volatilization, and nitrate leaching. These losses contribute to greenhouse gas emissions, affect air quality (NH 3 ), and are a substantial financial loss. This study compared three N placement methods (broadcast urea [BrUrea], broadcast incorporated urea [BrIncUrea], and injected urea ammonium nitrate [InjUAN]) and the presence or absence of N metabolite inhibitors (urease inhibitor [UI], urease plus nitrification inhibitor [UI+NI]). Fertilizer N was applied immediately before planting (150 kg N ha −1 ) to all treatments except for the control. Averaged over 3 yr (2015–2017), NH 3 losses were reduced by 34% from BrIncUrea, by 42–55% from BrUrea+UI+NI and BrIncUrea+UI+NI, and by 99% from InjUAN relative to BrUrea (21 kg N ha −1 ). On average, N application increased corn grain yields by 83% relative to the control (6 t ha −1 ). There were no annual yield differences among N placement methods. It was concluded that incorporation or injection of N in soil and use of urease and nitrification inhibitors reduced NH 3 emissions when N fertilizer was applied pre‐plant.

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