Preparation and Photocatalytic Hydrogen Production of Pink ZnS

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Abstract
With the continuous growth of global energy demand and the increasingly severe environmental issues, the extensive utilization of traditional fossil fuels has led to serious energy crises and environmental pollution problems. In this study, a hydrothermal method was employed, and by adding ethanolamine and controlling different temperatures, pink zinc sulfide with zinc vacancies was synthesized. UV-Vis DRS analysis indicated that the sample exhibited significant visible light absorption characteristics within the wavelength range of 500–550 nm. The presence of zinc vacancies was confirmed through XPS. Due to the existence of zinc vacancies, the sample demonstrated excellent photocatalytic hydrogen evolution activity without the need for co-catalysts, with the optimal sample achieving a hydrogen evolution rate of 7631.70 μmol h−1 g−1. Zinc vacancies can provide additional active sites, enhance catalytic efficiency, and promote the separation of photogenerated electrons and holes. Furthermore, the introduction of vacancies effectively reduces the bandgap of the material, significantly broadening its visible light absorption range. This work provides a new approach for enhancing hydrogen evolution in pure ZnS and offers novel strategies for the further design of ZnS-related photocatalysts.
Funding Information
  • National Natural Science Foundation of China (22275103, 2023TSGC0676, 2022TSGC2467, 2022CXY-01, 2021KC03)
  • Science and Technology Small and Medium-sized Enterprise Innovation Ability Enhancement Project of Shandong Province (22275103, 2023TSGC0676, 2022TSGC2467, 2022CXY-01, 2021KC03)
  • Industry–University–Research Collaborative Innovation Foundation (22275103, 2023TSGC0676, 2022TSGC2467, 2022CXY-01, 2021KC03)

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