Paramagnetic-Resonance Spectrum of $W^{5 +}$ in Rutile (Ti $O_{2}$ )

Author:

8 July 1966

journal article
research article
Published by American Physical Society (APS) in Physical Review B

Vol. 147 (1) , 264-267
DOI:10.1103/physrev.147.264

Abstract

The paramagnetic-resonance spectrum of

W^{5 +}

substitutional in Ti

O_{2}

was measured and analyzed. Both hyperfine lines and superhyperfine lines are observed. In the superhyperfine spectrum there is one group of relatively weak lines that is probably due to "forbidden" transitions. The

g

factors are:

g_{c} = 1.4431

g_{1 \bar{1} 0} = 1.5944

g_{110} = 1.4725

. The hyperfine coupling constants are

A_{c} = 63.7 \times 10^{- 4}

{cm}^{- 1}

A_{1 \bar{1} 0} = 92.5 \times 10^{- 4}

{cm}^{- 1}

A_{110} = 40.8 \times 10^{- 4}

{cm}^{- 1}

Keywords

This publication has 10 references indexed in Scilit:

Mechanism of Superhyperfine Structure in SnO2:V4+
The Journal of Chemical Physics, 1965
Spin Resonance of SnO2:V and the Vanadium 3d Electron Orbital
The Journal of Chemical Physics, 1965
Electron Spin Resonance of ${Mo}^{5 +}$ in Rutile
Physical Review B, 1964
Paramagnetic Resonance of Iron Group Elements in Rutile. I. The ${Ti}^{47}$ and ${Ti}^{49}$ hfs Interaction
Physical Review B, 1964
Optical spectra of several d1-electron systems
Journal of Physics and Chemistry of Solids, 1963
${Ti}^{47}$ and ${Ti}^{49}$ Hyperfine Structure in the Electron Spin Resonance of Titanium (III) Complexes
Physical Review B, 1962
Paramagnetic Resonance of $V^{4 +}$ in Ti $O_{2}$
Physical Review B, 1960
Properties of Rutile (Titanium Dioxide)
Reviews of Modern Physics, 1959
PARAMAGNETIC RESONANCE OF OCTACYANOTUNGSTATE(V)¹
Journal of the American Chemical Society, 1956
Paramagnetic resonance
Reports on Progress in Physics, 1953

Paramagnetic-Resonance Spectrum ofW5+in Rutile (TiO2)

Abstract

Keywords

Paramagnetic-Resonance Spectrum of $W^{5 +}$ in Rutile (Ti $O_{2}$ )