Relativistic configuration-interaction oscillator strengths for lowesttransitions in silver and gold isoelectronic sequences
Authors:
- 14 October 2009
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 80 (4) , 042505
Abstract
Relativistic oscillator strengths are computed for transitions in silver and gold isoelectronic sequences employing configuration-interaction method with numerical Dirac-Fock wave functions generated with noninteger outermost core shell occupation number. This method is optimized to represent efficiently the core-valence electron correlation that is known to be important for transitions under consideration. The presented results are compared with our earlier data computed with core-valence correlation represented in the semiclassical core polarization picture within single configuration Dirac-Fock scheme as well as available experimental values.
Keywords
This publication has 5 references indexed in Scilit:
- Relativistic configuration-interaction oscillator strength calculations withab initiomodel potential wavefunctionsJournal of Physics B: Atomic, Molecular and Optical Physics, 2003
- Relativistic configuration-interaction study of transition probabilities in mercury withab initiomodel potential wave functionsPhysical Review A, 2000
- The relativisticab initiomodel potential versus Dirac-Fock oscillator strengths for silver and gold isoelectronic sequencesJournal of Physics B: Atomic, Molecular and Optical Physics, 2000
- Relativistic Hartree-Fock oscillator strengths for the lowest s→p and p→d transitions in the first few members of the Ag(I) and Au(I) isoelectronic sequences, with allowance for cope polarizationJournal of Quantitative Spectroscopy and Radiative Transfer, 1979
- A multiconfiguration relativistic DIRAC-FOCK programComputer Physics Communications, 1975