Untersuchungen an Cyclopropanverbindungen, IV. Über die Bildung von Bicyclo[3.1.0]hexanol‐(2) aus Δ3‐Cyclohexenyl‐Derivaten
Authors:
- 1 November 1963
- journal article
- research article
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 96 (11) , 2937-2942
Abstract
Δ3‐Cyclohexenylamin (V;X = NH2) reagiert bei der Umsetzung mit salpetriger Säure teilweise unter Homoallylumlagerung und Bildung von Bicyclo[3.1.0]‐hexanol‐(2) (IV;X = OH). Bei der Acetolyse von Δ3‐Cyclohexenyltoluolsulfonat (V; X = OSO2C6H4–CH3(p)) wird ebenfalls in geringer Menge Bicyclo‐[3.1.0]hexanol‐(2) gefunden, während die Methanolyse praktisch nur Δ3‐Cyclo‐hexenylmethyläther ergibt.Keywords
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