Selenium makes the difference: protonation of [FeFe]-hydrogenase mimics with diselenolato ligands
- 6 February 2017
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 46 (9) , 2937-2947
Abstract
The synthetic models of the active site of an [FeFe]-hydrogenase containing a Sn atom in the bridgehead of the diselenato ligand, namely [Fe 2 (CO) 6 {μ-(SeCH 2 Se)SnMe 2 }], 3 and [Fe 2 (CO) 6 {μ-(SeCH 2 ) 2 SnMe 2 }], 4 have been synthesized and characterized by spectroscopic methods.Keywords
Funding Information
- Deutscher Akademischer Austauschdienst (PhD scholarship)
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