Regio- and Enantioselective Pd-Catalyzed Allylic Amination of Monosubsti­tuted Allylic Substrates with BocNHOMe

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Abstract
A new type of N-nucleophile has been developed in Pd-catalyzed asymmetric allylic amination with monosubstituted allyl substrates, affording corresponding branched allyl amines in high regio- and enantioselectivities. Either OMe or Boc group in products can be removed easily to provide primary amine derivatives with the optical purity unchanged.