Simple, Chemoselective, Catalytic Olefin Isomerization
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Open Access
- 14 November 2014
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 136 (48) , 16788-16791
Abstract
Catalytic amounts of Co(SaltBu,tBu)Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.Keywords
Funding Information
- Baxter International Foundation
- Amgen
- Nature et technologies (172618)
- Boehringer Ingelheim
- Alfred P. Sloan Foundation
- National Institute of General Medical Sciences (GM104180)
- Eli Lilly and Company
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