A new Al-MOF based on a unique column-shaped inorganic building unit exhibiting strongly hydrophilic sorption behaviour
- 8 August 2012
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 48 (76) , 9486-9488
Abstract
The new Al-based metal–organic framework [Al13(OH)27(H2O)6(BDC-NH2)3Cl6(C3H7OH)6] denoted CAU-6 (CAU = Christian-Albrechts-Universität) was solvothermally synthesized in 2-propanol and was thoroughly characterized. The framework structure exhibits a unique column-shaped inorganic building unit, which is based on stacked, corner-sharing Al13-clusters. The compound exhibits unprecedented hydrophilicity for metal–organic frameworks.Keywords
This publication has 19 references indexed in Scilit:
- Generalized Synthesis of Zeolite-Type Metal–Organic Frameworks Encapsulating Immobilized Transition-Metal ClustersJournal of the American Chemical Society, 2012
- Hydrogen Storage in Metal–Organic FrameworksChemical Reviews, 2011
- p-Xylene-Selective Metal–Organic Frameworks: A Case of Topology-Directed SelectivityJournal of the American Chemical Society, 2011
- Porous Indium–Organic Frameworks and Systematization of Structural Building BlocksAngewandte Chemie International Edition, 2011
- Engineering Metal Organic Frameworks for Heterogeneous CatalysisChemical Reviews, 2010
- Occurrence of Uncommon Infinite Chains Consisting of Edge-Sharing Octahedra in a Porous Metal Organic Framework-Type Aluminum Pyromellitate Al4(OH)8[C10O8H2] (MIL-120): Synthesis, Structure, and Gas Sorption PropertiesChemistry of Materials, 2009
- Synthesis, Single-Crystal X-ray Microdiffraction, and NMR Characterizations of the Giant Pore Metal-Organic Framework Aluminum Trimesate MIL-100Chemistry of Materials, 2009
- A microdiffraction set-up for nanoporous metal–organic-framework-type solidsNature Materials, 2007
- Synthesis and crystal structures of supramolecular compounds of polynuclear aluminum(III) aqua hydroxo complexes with cucurbit[6]urilRussian Chemical Bulletin, 2006
- A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL‐53) Upon HydrationChemistry – A European Journal, 2004