FeNCN and Fe(NCNH)2: Synthesis, Structure, and Magnetic Properties of a Nitrogen‐Based Pseudo‐oxide and ‐hydroxide of Divalent Iron
- 26 January 2009
- journal article
- research article
- Published by Wiley in Chemistry – A European Journal
- Vol. 15 (7) , 1558-1561
Abstract
Iron man challenge: Iron carbodiimide, FeNCN, and its precursor iron (bis)monohydrocyanamide, Fe(NCNH)2, have been synthesized and physically characterized. Both FeNCN and Fe(NCNH)2 exhibit nitrogen‐mediated antiferromagnetic superexchange interactions with reduced magnetic moments very similar, but not identical, to the correlated 3d oxides. magnified image No AbstractKeywords
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