INFRARED STUDY OF THE N—OH GROUP IN ALPHA AND BETA OXIMES
Authors:
- Ann PalmAPAnn Palm
- Harold WerbinHWHarold Werbin
- 1 September 1954
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 32 (9) , 858-863
Abstract
The O—H bending and N—O stretching vibrations were studied in four pairs of isomeric oximes. A band at 1265 cm.−1, characteristic of the solution spectra of the α oximes, is identified with the O—H bending mode. Tentative assignments for the N—O stretching vibration both in solid and solution spectra are advanced. The β isomers show a distinct shift of the band associated with the N—O mode from about 950 cm.−1 in the solid to about 930 cm.−1 in solution.Keywords
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