Castor‐based derivatives: Synthesis of some acrylate esters
Authors:
- 1 September 1966
- journal article
- research article
- Published by Wiley in Journal of the American Oil Chemists' Society
- Vol. 43 (9) , 542-545
Abstract
Acrylate esters of various hydroxy acid derivatives obtainable from castor oil have been synthesized and characterized. Synthetic methods evaluated include acid‐ and base‐catalyzed alcoholysis of methyl acrylate, esterification with acrylic acid, acrylyl chloride, or acrylic anhydride, and esterification with ॆ‐chloropropionyl chloride or anhydride followed by dehydrohalogenation. The two‐step esterification‐dehydrohalogenation procedure gives most satisfactory yields and purity. Preparation, purification, and characterization of the compounds are described and the various synthetic methods are evaluated.Keywords
This publication has 17 references indexed in Scilit:
- Enantiomorphism in the Helical Aggregate of Lithium 12-HydroxystearateJournal of the American Chemical Society, 1965
- Preparation of phosphorus esters of long‐chain hydroxy fatty acidsJournal of the American Oil Chemists' Society, 1964
- 171. Reaction of αβ-unsaturated acid chlorides with alcohols in the presence of tertiary aminesJournal of the Chemical Society (Resumed), 1964
- Castor‐based derivatives: Synthesis of some amidesJournal of the American Oil Chemists' Society, 1963
- To-day's DrugsBMJ, 1959
- Kinetics of Reactions of Acyl Chlorides. IV.1 Solvolysis of Acyl Halides in DimethylformamideJournal of the American Chemical Society, 1956
- Preparations of N,N-DimethylamidesJournal of the American Chemical Society, 1954
- The Preparation of Acrylyl ChlorideJournal of the American Chemical Society, 1950
- Copolymerization of Alkyl Acrylates and Alkyl Maleates. Some Kinetic Studies on Copolymerization1Journal of the American Chemical Society, 1942
- Über Ricinolsäure und 12‐Oxy‐stearinsäure.Berichte der deutschen chemischen Gesellschaft (A and B Series), 1933