Sorption behaviour in a unique 3,12-connected zinc–organic framework with 2.4 nm cages
Authors:
- 1 January 2013
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry A
- Vol. 1 (36) , 10631-10634
Abstract
A polyhedral metal–organic framework (FJI-2) has been synthesized based on rare hexanuclear zinc clusters, which comprises 2.4 nm double-walled octahedral cages topologically featuring a new 3,12-connected structure. FJI-2 has a good H2 uptake capacity of 149.7 cm3 g−1 (1.34 wt %) at 77 K and 1.0 bar, and the IAST calculation predicts highly selective adsorption of CO2 over N2 and CH4.Keywords
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