Utilizing enantiomerically pure organic spacers for anion-centred clusters in a hybrid inorganic–organic lead-halide crystal
Open Access
- 19 June 2025
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 61 (58) , 10855-10858
Abstract
We report the synthesis and structure of the novel, chiral material (S-2AH)4[Pb2Br7]Br with a layered structure. Through the use of enantiomerically pure precursors, bromide-centered clusters within the non-polar, organic spacer layer are formed.Keywords
Funding Information
- European Research Council (852084 – TWIST)
This publication has 20 references indexed in Scilit:
- Orientation-Driven Chirality Funnels in Chiral Low-Dimensional Lead-Halide Perovskite HeterostructuresJournal of the American Chemical Society, 2025
- Efficient Green Spin Light-Emitting Diodes Enabled by Ultrafast Energy- and Spin-Funneling in Chiral PerovskitesJournal of the American Chemical Society, 2024
- Incorporating Copper(I) Clusters into Lead Halide Perovskite through Mediation of Zwitterionic LinkersChemistry of Materials, 2024
- Spin Quantum Dot Light‐Emitting Diodes Enabled by 2D Chiral Perovskite with Spin‐Dependent Carrier TransportAdvanced Materials, 2023
- Quantum confinement effect on the electronic and optical properties of two-dimensional halide perovskitesComputational Materials Science, 2023
- Structural descriptor for enhanced spin-splitting in 2D hybrid perovskitesNature Communications, 2021
- Organic-to-inorganic structural chirality transfer in a 2D hybrid perovskite and impact on Rashba-Dresselhaus spin-orbit couplingNature Communications, 2020
- Circularly polarized light detection using chiral hybrid perovskiteNature Communications, 2019
- Chiral 2D Perovskites with a High Degree of Circularly Polarized PhotoluminescenceACS Nano, 2019
- Low-Dimensional Organometal Halide PerovskitesACS Energy Letters, 2017