Changes in Heavy Oil Saturates and Aromatics in the Presence of Microwave Radiation and Iron-Based Nanoparticles

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Abstract
Our knowledge of electromagnetic heating’s effect on heavy oil upgrading is largely based on very limited data. The aim of the present research was thus to study in detail the effect of microwave exposure in the absence and presence of nanosized magnetite on the composition of heavy oil. The obtained data reveal that the use of nanosized magnetite improves not only microwave radiation application as a result of its absorption and release of thermal energy but also that these nanoparticles have a catalytic ability to break carbon–heteroatom bonds in the composition of resins and asphaltene molecules. In fact, the overall reduction in asphaltenes or resins does not always adequately describe very important changes in asphaltene composition. Even a small fraction of broken carbon–heteroatom bonds can lead to an increase in the mobility of asphaltenes. Moreover, this study has shed light on the important evidence for asphaltenes’ transformation, which was found to be the formation of light aromatic compounds, such as alkylbenzenes, naphthalenes and phenanthrenes. These compounds were fixed in the composition of the aromatic fraction. We believe that these compounds could be the fragments obtained from asphaltenes’ degradation. The evidence from this study points toward the idea that asphaltenes’ destruction is crucial for increasing oil mobility in the reservoir rock during its thermal stimulation.

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