Hydrogen and Oxygen Evolution in a Membrane Photoreactor Using Suspended Nanosized Au/TiO2 and Au/CeO2

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Abstract
Photocatalysis combined with membrane technology could offer an enormous potential for power generation in a renewable and sustainable way. Herein, we describe the one-step hydrogen and oxygen evolution through a photocatalytic membrane reactor. Experimental tests were carried out by means of a two-compartment cell in which a modified Nafion membrane separated the oxygen and hydrogen evolution semi-cells, while iron ions permeating through the membrane acted as a redox mediator. Nanosized Au/TiO2 and Au/CeO2 were employed as suspended photocatalysts for hydrogen and oxygen generation, respectively. The influence of initial Fe3+ ion concentration, ranging from 5 to 20 mM, was investigated, and the best results in terms of hydrogen and oxygen evolution were registered by working with 5 mM Fe3+. The positive effect of gold on the overall water splitting was confirmed by comparing the photocatalytic results obtained with the modified/unmodified titania and ceria. Au-loading played a key role for controlling the photocatalytic activity, and the optimal percentage for hydrogen and oxygen generation was 0.25 wt%. Under irradiation with visible light, hydrogen and oxygen were produced in stoichiometric amounts. The crucial role of the couple Fe3+/Fe2+ and of the membrane on the performance of the overall photocatalytic system was found.

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