Strict self-assembly of [Fe(cyclam)] 3+ and [hydrogenbis(1,1′-ferrocenedicarboxylate)] 3– into a novel mixed-valent one-dimensional polymer containing an Fe III N 4 O 2 chromophore
Authors:
- Sean D. ChristieSCSean D. Christie
- S. SubramanianSSS. Subramanian
- L. K. ThompsonLTL. K. Thompson
- M. J. ZaworotkoMZM. J. Zaworotko
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 2563-2564
Abstract
trans-[FeIII(cyclam)][{Fc(CO2)2}2H], 1, (cyclam = 1,4,8,11-tetraazacyclotetradecane; [Fc(CO2)2]2–= 1,1′-ferrocenedicarboxylate) strictly self-assembles via FeIII–carboxylate covalent bonds and hydrogenbiscarboxylate hydrogen bonds to form a one-dimensional polymer that contains the first crystallographically characterized FeIIIN4O2 chromopore.Keywords
This publication has 21 references indexed in Scilit:
- Interwoven two- and three-dimensional coordination polymers through self-assembly of Cu I cations with linear bidentate ligandsJournal of the Chemical Society, Chemical Communications, 1994
- Manifestations of noncovalent interactions in the solid state. 3. X-ray crystal structures of [H4(cyclam)][FeCl5(OH2)](Cl)2 and [H4(cyclam)][CF3COO]4, two network hydrogen bonded solidsCanadian Journal of Chemistry, 1993
- The hydrogen bond and crystal engineeringChemical Society Reviews, 1993
- Self-assembly of [H4(cyclam)]Cl4(cylam = 1,4,8,11-tetraazacyclotetradecane) into a 3-D polymeric network with microchannels that sustain a symmetrical 1-D polymer of water moleculesJournal of the Chemical Society, Chemical Communications, 1993
- Structure and properties of a bimetallic complex with a conjugated bridge between iron atoms in two macrocyclesInorganic Chemistry, 1992
- Coordination polymerisation of a binuclear copper(II) macrocyclic cation through self-assemblyJournal of the Chemical Society, Chemical Communications, 1992
- Molecular recognition in the solid state: controlled assembly of hydrogen-bonded molecular sheetsJournal of the American Chemical Society, 1991
- Use of hydrogen bonds to control molecular aggregation. Self-assembly of three-dimensional networks with large chambersJournal of the American Chemical Society, 1991
- The crystal and molecular structure of 1,1'-ferrocenedicarboxylic acid (triclinic modification): neutron and X-ray diffraction studies at 78 K and 298 KActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1979
- Synthesis of metal complexes with macrocyclic ligands having prescribed patterns of unsaturation. Oxidative dehydrogenation of fused-ring systems involving charged, delocalized six-membered chelate ringsInorganic Chemistry, 1972