Amorphous zinc borate as a simple standard for baseline correction in Raman spectra
Open Access
- 31 May 2017
- journal article
- research article
- Published by Wiley in Journal of Raman Spectroscopy
- Vol. 48 (11) , 1644-1653
Abstract
In this paper, our research group proposes a simple solution to a usual problem that appears in the Raman analysis of some substances, which is the presence of weak Raman signals, probably in combination with a high‐intensity luminescence background, affected by the presence of distortions in the baseline. Under this condition, the spectroscopist has to face spectra hard to edit and correct and thus hard to study. There are already some standard solutions that allow the correction of spectra from relative intensity to absolute intensity that also solves this problem and also allow quantitative analyses. But these solutions imply expensive standards or devices that could not be a worthy option when not working in absolute intensity or the Raman analyses stay at qualitative level and a quantitative study is not needed. The alternative Do It Yourself solution proposed in this paper is based on the use of amorphous zinc borate, an easy‐to‐find substance, which after a simple processing allows us to correct the baseline of Raman spectra qualitatively, offering a useful and economic reference when an absolute intensity correction is not needed. In order to evaluate the effectiveness of this procedure, some spectra were corrected using amorphous zinc borate and then compared the signal‐to‐noise ratio of some Raman signals before and after this correction. Copyright © 2017 John Wiley & Sons, Ltd.Keywords
Funding Information
- Spanish Ministry of Economy, Industry and Competitiveness (MINECO) (ESP2013-48427-C3-2-R, ESP2014-55851-C2-2-P)
This publication has 17 references indexed in Scilit:
- Analysis of Arctic ices by Remote Raman SpectroscopySpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2011
- Standardization of Raman spectra for transfer of spectral libraries across different instrumentsThe Analyst, 2011
- A Model-Free, Fully Automated Baseline-Removal Method for Raman SpectraApplied Spectroscopy, 2011
- A Raman spectral study of stream waters and efflorescent salts in Rio Tinto, SpainSpectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2009
- Relative Intensity Correction of Raman Spectrometers: NIST SRMs 2241 through 2243 for 785 nm, 532 nm, and 488 nm/514.5 nm ExcitationApplied Spectroscopy, 2007
- Comparative micro‐Raman study of the Nakhla and Vaca Muerta meteoritesJournal of Raman Spectroscopy, 2004
- Structural Characterization and Chemistry of the Industrially Important Zinc Borate, Zn[B3O4(OH)3]Chemistry of Materials, 2003
- Estimation of crystallinity in polyethylene by Raman spectroscopyJournal of Raman Spectroscopy, 1993
- Polarized Raman spectra of aqueous solutions and band component analysisJournal of Molecular Structure, 1986
- Two accurate methods to obtain the spectral sensitivity of a Raman spectrometer deviceJournal of Raman Spectroscopy, 1982