Self-Organized Heteroditopic Macrocyclic Superstructures
Authors:
- 22 July 2003
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 5 (17) , 3073-3076
Abstract
The synthesis of heteroditopic macrocyclic ureido receptors and of their NaX complexes is described. NMR studies and determination of the crystal structure show the formation of self-organized dimeric or polymeric superstructures by a cooperative macrocyclic cation complexation, anion−hydrogen bonding, and π−π stacking interactions. Membrane transport experiments show a direct relation between the synergetic ion-pair recognition and the transport properties of these molecular information transfer devices.Keywords
This publication has 7 references indexed in Scilit:
- Synergistic Pseudo-Hydroxide Extraction: Synergism and Anion Selectivity in Sodium Extraction Using a Crown Ether and a Series of Weak Lipophilic AcidsAnalytical Chemistry, 2003
- Synthetic models of cation-conducting channelsChemical Society Reviews, 2001
- Chiral Recognition in Bis-Urea-Based Aggregates and Organogels through Cooperative InteractionsAngewandte Chemie International Edition, 2001
- Characterization of Hydrogen-Bonded Aggregates in Chloroform by Electrospray Ionization Mass SpectrometryThe Journal of Organic Chemistry, 1996
- Supramolecular Chemistry1995
- Encoding and decoding hydrogen-bond patterns of organic compoundsAccounts of Chemical Research, 1990
- Zur Lehre von der Wirkung der SalzeNaunyn-Schmiedeberg's Archives of Pharmacology, 1888