On chirality induction in the crystalline solid-containing sandwich-type [Ln(α-PW11O39)2]11−polyoxotungstate and proline
- 23 September 2016
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in RSC Advances
- Vol. 6 (94) , 91494-91507
Abstract
For the racemisation, the [Ln(α-PW11O39)2]11−polyanion with light Ln experienced the ‘on-site rotation’ mechanism, while the [Ln(α-PW11O39)2]11−polyanion with heavy Ln followed the “dissociation–association” mechanism.Keywords
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