Nickel‐Catalyzed Amination of Aryl Pivalates by the Cleavage of Aryl C-O Bonds
- 30 March 2010
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 49 (16) , 2929-2932
Abstract
Catalytic amination: The title reaction demonstrates the use of aryl carboxylates as suitable electrophilic coupling substrates in catalytic amination reactions. N-heterocyclic carbene ligands and NaOtBu promote the amination of aryl pivalates through the cleavage of normally unreactive aryl carbon–oxygen bonds (see scheme; cod=cyclooctadiene).Keywords
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