Triphenylbis(2,4,5-trifluoro-3-methoxybenzoato)antimony(V)
Authors:
Open Access
- 20 September 2008
- journal article
- other
- Published by International Union of Crystallography (IUCr) in Acta Crystallographica Section E Structure Reports Online
- Vol. 64 (10) , m1303
Abstract
In the title compound, [Sb(C(6)H(5))(3)(C(8)H(4)F(3)O(3))(2)], the Sb atom lies on an inversion centre and exhibits a trigonal bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl-ate groups and the equatorial positions occupied by C atoms of the phenyl groups. Intra-molecular C-H⋯O hydrogen bonds stabilize the mol-ecular conformation. In the crystal structure, mol-ecules are connected by inter-molecular C-H⋯O hydrogen-bonding inter-actions, forming a layer structure parallel to (01).Keywords
This publication has 3 references indexed in Scilit:
- A short history of SHELXActa Crystallographica Section A Foundations of Crystallography, 2007
- Second determination of the structure of dimeric triphenylstibine oxideActa Crystallographica Section C Crystal Structure Communications, 1987
- Synthesis of tetraphenylstibonium alkyl- and aryl- sulphonates. Crystal structure of tetraphenylstibonium benzenesulphonate hydrateJournal of Organometallic Chemistry, 1985