From silicon to silicones without dimethyldichlorosilane: direct green mechanochemical synthesis of methylmethoxysilanes from silicon and dimethyl ether
- 25 April 2024
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Green Chemistry
- Vol. 26 (11) , 6656-6665
Abstract
First gram-scale synthesis of methylmethoxysilanes via mechanochemical direct reaction of Si with dimethyl ether, achieving nearly 100% silicon conversion and high selectivity for dimethylsilyl-containing products.Keywords
Funding Information
- Russian Science Foundation (22-13-00279)
This publication has 41 references indexed in Scilit:
- Recent Advances in Rochow‐Müller Process Research: Driving to Molecular Catalysis and to A More Sustainable Silicone IndustryChemCatChem, 2019
- Mechanochemical Method and Equipment Design for Obtaining AlcoxysilanesChemical and Petroleum Engineering, 2019
- Geminal2J(29Si‐O‐29Si) couplings in oligosiloxanes and their relation to direct1J(29Si‐13C) couplingsMagnetic Resonance in Chemistry, 2011
- Effects of Multiple Promotion of the Direct Synthesis Contact Mass with P, Zn, and Sn on the Synthesis of MethylchlorosilanesCatalysis Letters, 2009
- Activation of CuSi and CuZnSnSi contact masses for the direct synthesis of methylchlorosilanesReaction Kinetics, Mechanisms and Catalysis, 1996
- Effect of Silicon Oxide Thickness on theDirect Synthesis of DimethyldichlorosilaneJournal of Catalysis, 1996
- The Effect of Zn Promoter on Enhanced Diffusion During Catalytic Formation of MethylchlorosilanesJournal of Catalysis, 1994
- Kinetics of methylchlorosilane formation on Zn‐promoted Cu3SiInternational Journal of Chemical Kinetics, 1987
- Silicon and Silicones1987
- Active site formation in the direct process for methylchlorosilanesJournal of Catalysis, 1986