Nickel-catalyzed coupling reactions of alkenes
Authors:
- 1 January 2008
- journal article
- Published by Walter de Gruyter GmbH in Pure and Applied Chemistry
- Vol. 80 (5) , 929-939
Abstract
Several reactions of simple, unactivated alkenes with electrophiles under Ni(0) catalysis are discussed. The coupling of olefins with aldehydes and silyl triflates provides allylic or homoallylic alcohol derivatives, depending on the supporting ligands and, to a lesser extent, the substrates employed. Reaction of alkenes with isocyanates yields N-alkyl acrylamides. In these methods, alkenes act as the functional equivalents of alkenyl- and allylmetal reagents.Keywords
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